MEA英文MSDS汇总.docx
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MEA英文MSDS汇总.docx
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MEA英文MSDS汇总
MaterialSafetyDataSheet(MSDS)
1.PRODUCTANDCOMPANYIDENTIFICATION
Productname:
Monoethanolamine
ProductNumber:
MEA
Supplier:
LOTTECHEMICAL.
LotteTowerBldg.,395-67Shindaebangdong,Dongjak-SeoulKOREA
(Zipcode:
156-012)
TEL:
82-2-829-4114
FAX:
82-2-843-1010
2.HAZARDSIDENTIFICATION
EmergencyOverview
OSHAHazardsNoknownOSHAhazards
GHSClassification
Skinirritation(Category3)
GHSLabelelements,includingprecautionarystatements
Pictogram
SignalwordDanger
Hazardstatement(s)
H302+H312+H332Harmfulifswallowed,incontactwithskinorifinhaled.
H314Causessevereskinburnsandeyedamage.
H412Harmfultoaquaticlifewithlonglastingeffects.
Precautionarystatement(s)
P273Avoidreleasetotheenvironment.
P280Wearprotectivegloves/protectiveclothing/eyeprotection/face
protection.
P305+P351+P338IFINEYES:
Rinsecautiouslywithwaterforseveralminutes.Remove
contactlenses,ifpresentandeasytodo.Continuerinsing.
P310ImmediatelycallaPOISONCENTERordoctor/physician.
SupplementalHazardnone
Statements
Otherhazard
Thissubstance/mixturecontainsnocomponentsconsideredtobeeitherpersistent,
bioaccumulativeandtoxic(PBT),orverypersistentandverybioaccumulative(vPvB)atlevelsof0.1%orhigher.
3.COMPOSITION/INFORMATIONONINGREDIENTS
Synonyms:
Monoethanolamine
2-Aminoethylalcohol
2-Aminoethanol
Formula:
C2H7NO
CAS-No.
EC-No.
Index-No.
Concentration
141-43-5
205-483-3
603-030-00-8
4.FIRSTAIDMEASURES
Generaladvice
Consultaphysician.Showthissafetydatasheettothedoctorinattendance.
Ifinhaled
Ifbreathedin,movepersonintofreshair.Ifnotbreathing,giveartificialrespiration.Consultaphysician.
Incaseofskincontact
Washoffwithsoapandplentyofwater.Consultaphysician.
Incaseofeyecontact
Flusheyeswithwaterasaprecaution.
Ifswallowed
Nevergiveanythingbymouthtoanunconsciousperson.Rinsemouthwithwater.Consultaphysician.
5.FIRE-FIGHTINGMEASURES
Suitableextinguishingmedia
Usewaterspray,alcohol-resistantfoam,drychemicalorcarbondioxide.
Specialhazardsarisingfromthesubstanceormixture
Carbonoxides,Nitrogenoxides(NOx)
Adviceforfirefighters
Wearself-containedbreathingapparatusforfirefightingifnecessary.
Furtherinformation
Usewaterspraytocoolunopenedcontainers.
6.ACCIDENTALRELEASEMEASURES
Personalprecautions
Usepersonalprotectiveequipment.Avoiddustformation.Avoidbreathingvapors,mistorgas.
Ensureadequateventilation.Removeallsourcesofignition.Evacuatepersonneltosafeareas.
Bewareofvapoursaccumulatingtoformexplosiveconcentrations.Vapourscanaccumulateinlow
areas.
Environmentalprecautions
Preventfurtherleakageorspillageifsafetodoso.Donotletproductenterdrains.Dischargeintothe
environmentmustbeavoided.
Methodsandmaterialsforcontainmentandcleaningup
Containspillage,andthencollectwithanelectricallyprotectedvacuumcleanerorbywet-brushingand
placeincontainerfordisposalaccordingtolocalregulations.Keepinsuitable,closed
containersfordisposal.
7.HANDLINGANDSTORAGE
Precautionsforsafehandling
Avoidcontactwithskinandeyes.Avoidinhalationofvapourormist.
Keepawayfromsourcesofignition-Nosmoking.Takemeasurestopreventthebuildupof
electrostaticcharge.
Conditionsforsafestorage,includinganyincompatibilities
Storeincoolplace.Keepcontainertightlyclosedinadryandwell-ventilatedplace.Containerswhich
areopenedmustbecarefullyresealedandkeptuprighttopreventleakage.
8.EXPOSURECONTROLS/PERSONALPROTECTION
Controlparameters
Componentswithworkplacecontrolparameters
Exposurecontrols
Appropriateengineeringcontrols
Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Washhandsbeforebreaksand
attheendofworkday.
Personalprotectiveequipment
Eye/faceprotection
Tightlyfittingsafetygoggles.Faceshield(8-inchminimum).Useequipmentforeyeprotection
testedandapprovedunderappropriategovernmentstandardssuchasNIOSH(US)orEN
166(EU).
Skinprotection
Handlewithgloves.Glovesmustbeinspectedpriortouse.Usepropergloveremovaltechnique
(withouttouchingglove'soutersurface)toavoidskincontactwiththisproduct.Disposeof
contaminatedglovesafteruseinaccordancewithapplicablelawsandgoodlaboratorypractices.
Washanddryhands.
TheselectedprotectivegloveshavetosatisfythespecificationsofEUDirective89/686/EECand
thestandardEN374derivedfromit.
Fullcontact
Material:
Naturelatex/chloroprene
Minimumlayerthickness:
0,6mm
Breakthroughtime:
480min
Materialtested:
Lapren®(KCL706/AldrichZ677558,SizeM)
Splashcontact
Material:
Nitrilerubber
Minimumlayerthickness:
0,2mm
Breakthroughtime:
30min
Materialtested:
Dermatril®P(KCL743/AldrichZ677388,SizeM)
datasource:
KCLGmbH,D-36124Eichenzell,phone+49(0)665987300,e-mailsales@kcl.de,
testmethod:
EN374
Ifusedinsolution,ormixedwithothersubstances,andunderconditionswhichdifferfromEN374,
contactthesupplieroftheCEapprovedgloves.Thisrecommendationisadvisoryonlyandmust
beevaluatedbyanindustrialhygienistandsafetyofficerfamiliarwiththespecificsituationof
anticipatedusebyourcustomers.Itshouldnotbeconstruedasofferinganapprovalforany
specificusescenario.
BodyProtection
Completesuitprotectingagainstchemicals,Thetypeofprotectiveequipmentmustbeselected
accordingtotheconcentrationandamountofthedangeroussubstanceatthespecificworkplace.
Respiratoryprotection
Whereriskassessmentshowsair-purifyingrespiratorsareappropriateuseafull-facerespirator
withmulti-purposecombination(US)ortypeABEK(EN14387)respiratorcartridgesasabackup
toengineeringcontrols.Iftherespiratoristhesolemeansofprotection,useafull-facesuppliedair
respirator.Userespiratorsandcomponentstestedandapprovedunderappropriategovernment
standardssuchasNIOSH(US)orCEN(EU).
Controlofenvironmentalexposure
Preventfurtherleakageorspillageifsafetodoso.Donotletproductenterdrains.Dischargeinto
theenvironmentmustbeavoided.
9.PHYSICALANDCHEMICALPROPERTIES
Appearance
FormLiquidat25℃
ColourColourless
Safetydata
pHNodataavailable
Meltingpoint/freezingpoint10-11°C-lit.
Boilingpoint171°C-lit.
Flashpoint96°C–closedup
IgnitiontemperatureNodataavailable
Auto-ignitiontemperatureNodataavailable
LowerexplosionlimitNodataavailable
UpperexplosionlimitNodataavailable
VapourpressureNodataavailable
Molecularweight≒61.08
WatersolubilityNodataavailable
Partitioncoefficient:
n-octanol/waterNodataavailable
RelativevapourdensityNodataavailable
OdourNodataavailable
OdourThresholdNodataavailable
EvaporationrateNodataavailable
10.STABILITYANDREACTIVITY
Reactivity
Nodataavailable
Chemicalstability
Absorbscarbondioxide(CO2)fromair.Stableunderrecommendedstorageconditions.
Possibilityofhazardousreactions
Nodataavailable
Conditionstoavoid
Exposuretomoisture.Heat,flamesandsparks.
Materialstoavoid
Strongacidsandoxidizingagents,Iron,Copper,Brass,Rubber
Hazardousdecompositionproducts
Otherdecompositionproducts-Nodataavailable
11.TOXICOLOGICALINFORMATION
Acutetoxicity
LD50Oral-Rat-1.720mg/kg
Inhalation:
Materialisextremelydestructivetothetissueofthemucousmembranesand
upperrespiratory
LD50Dermal-Rabbit-1.015mg/kg
Skincorrosion/irritation
Nodataavailable
Seriouseyedamage/eyeirritation
Eyes-Rabbit
Result:
Severeeyeirritation
Respiratoryorskinsensitization
Nodataavailable
Germcellmutagenicity
Nodataavailable
Carcinogenicity
IARC:
Nocomponentofthisproductpresentatlevelsgreaterthanorequalto0.1%isidentifiedas
probable,possibleorconfirmedhumancarcinogenbyIARC.
12.ECOLOGICALINFORMATION
Toxicity
ToxicitytofishLC50-Pimephalespromelas(fatheadminnow)-227mg/l-96h
ToxicitytodaphniaandEC50-Daphniamagna(Waterflea)-65mg/l-48h
otheraquaticinvertebrates
ToxicitytoalgaeEC50-Desmodesmussubspicatus(greenalgae)-15mg/l-72h
Persistenceanddegradability
Nodataavailable
Bioaccumulativepotential
Nodataavailable
Mobilityinsoil
nodataavailable
PBTandvPvBassessment
Thissubstance/mixturecontainsnocomponentsconsideredtobeeitherpersistent,
bioaccumulativeandtoxic(PBT),orverypersistentandverybioaccumulative(vPvB)atlevelsof
0.1%orhigher.
Otheradverseeffects
Harmfultoaquaticlifewithlonglastingeffects.
13.DISPOSALCONSIDERATIONS
Product
Thiscombustiblematerialmaybeburnedinachemicalincineratorequippedwithanafterburner
andscrubber.Offersurplusandnon-recyclablesolutionstoalicenseddisposalcompany.
Contaminatedpackaging
Disposeofasunusedproduct.
14.TRANSPORTINFORMATION
UNnumber
ARD/RID:
2491IMDG:
2491IATA:
2491
UNpropershippingname
ARD/RID:
ETHANOLAMINE
IMDG:
ETHANOLAMINE
IATA:
Ethanolamine
Transporthazardclass
ADR/RID:
8IMDG:
8IATA:
8
Packinggroup
ADR/RID:
IIIIMDG:
IIIIATA:
III
Environmentalhazard
ADR/RID:
noIMDGMarinepollutant:
noIATA:
no
ExportHS-code
2922110001(China)
Others
Followallregulationsinyourcountry.
15.REGULATORYINFORMATION
ThissafetydatasheetcomplieswiththerequirementsofRegulation(EC)No.1907/2006.
Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture
Nodataavailable
ChemicalSafetyAssessment
Forthisproductachemicalsafetyassessmentwasnotcarriedout
16.OTHERINF
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