化工热力学翻译Word文档格式.docx
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化工热力学翻译Word文档格式.docx
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所有的单项热力学性质都能在12.5秒内从亥姆霍兹能量中计算出来,所用公式如下:
和
其中ρ和T是混合物的密度和温度,ρr(x)和Tr(x)是减少量,通过下式计算:
参数β和γ分别用来定义减少的温度和密度线的形状。
这些减少的参数和混合物的临界参数不同,它是通过对混合模型的其他参数的实验数据的非线性拟合而确定的。
12.9计算热力学性质的软件
有各种各样的软件包能运行文章中提到的状态方程,其中有两个程序,一是REFPROP,可以从NIST(www.nist.gov/srd/nist23.htm)获得;
二是ThermoFluids(www.FirstGmbH.de),由Wagner和他的同事在德国的鲁尔大学开发。
即可以用程序应用状态方程来计算热力学性质又可以用动态衔接库(DLL)在定义用户应用中来计算性质,例如MicrosoftExcel.例如,这个程序也能算出影响焓值的压力大小,它是基于iso-property线用户提供的输入而产生的。
尽管在大多数情况下推荐使用易于编程的算法,但是它也能导致新的问题。
在档案文献里从程序获得的价值常常被成为数据源。
因为被用来为某种流体产生数据的状态方程可能在之后的程序版本中不断更新,这样的一个参考是模糊的也可能导致得不到科学结果。
即使使用有效的商用软件,引用用来计算性能数据和相关参数的状态方程也是非常重要的。
因此软件开发商必须为用户提供原始参考资料。
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