US4954274Word文档下载推荐.docx
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JamesG.Jolly,5233Halls
FerryDr.,BatonRouge,La.70817
Appl.No.:
363,443
Filed:
Jun.6,1989
4,204,9695/1980Papayetal.....................·
…252/45
4,225,4889/1980Horodyskyetal...........……252/45
4,240,95812/1980Braid......................一~……252/45
4,563,3021/1986Griffinetal..........................252!
45
4,645,6102/1987Bornetal............................252/45
4,710,27312/1987Okamoto.........~二~~.~~一….568/18
4︸6
尸J7
PrimaryExaminer-WilliamR.Dixon,Jr.
AssistantExaminer-JerryD.Johnson
RelatedU.S.ApplicationData
[63]ContinuationofSer.No.138,937,Dec.29,1987,aban-
doned.
玩t.C!
.5
U.S.C!
.
..…C10M135/02
252/45;
252/48.8;
FieldofSearch
Re
568/18
252/45,48.8;
ferencesCited
们J刀8]司
尸、︶尺曰尸、︶尸、︶
一..Ll..Ll..Ll..L
U.
2,565,493
S.PATENTDOCUMENTS
8/1951
3,410,80011/1968
3,697,49910/1972
Gardner.~~~~~~.一一一:
.~…,.252/45
Fordeta1..........................252/48.8
Myers一~~.........................252/48.8
Is}}aBS}cr
Sulfurizedolefinsareproducedbyreactingsulfur
monochloridewithamonoolefm(e.g.isobutene)inthe
presenceofminoramountsofanactiveLewisacid(e.g.
ferricchloride)toformanadduct,reactingtheadduct
withsulfurandsodiumsulfideinanaqueousalkanol
madeataratioof0.02-0.4gramatomofsulfurpergram
moleofsodiumsulfideandthenrecoveringthereaction
product.Olefinpolysulfidesobtainedbythismethod
aresolubleinbothmineralandsyntheticlubricatingoils
(includingthoseofthepolyalphaolefintype)andare
usableasextremepressureadditiveswhenincorporated
intosuchlubricatingoils.Sulfurized烯烃反应产生的硫
方法用monoolefm(例如isobutene)
较小的数量存在一个活跃的路易斯酸(例句。
氯化铁)形成一个adduct,反应adduct的
用硫和钠硫化物在水alkanol
在比例为0.02-0.4克每克的硫原子
鼹鼠的钠硫化物,然后恢复的反应
产品。
烯烃polysulfides得到这个方法
两个都是溶于油和合成润滑油矿物吗
16Claims,NoDrawings
1
SULFURIZEDOLEFINEXTREMEPRESSURE
ADDITIVES
ThisapplicationisacontinuationofapplicationSer.
No.138,937,filedDec.29,1987nowabandoned.
BACKGROUNDOFTHEINVENTION
Thisinventionrelatestosulfurizedolefinsand,in
2
Inaccordancewiththeinvention,thestartingolefins
arethemonoethylenicallyunsaturatedaliphatichydro-
carbonsreferredtoasaliphaticmonoolefinscontaining
3toabout6carbonatoms.Theseinclude1-butene,
52-butene,isobutene,1-pentene,2-pentene,2-methyl-l-
butene,3-methyl-l-butene,2-methyl-2-butene,1-hex-
ene,2-hexene,3-hexene,2-methyl-lpentene,2-methyl-
2-pentene,2-ethyl-2-buteneandthelikeincludingmix-
turesthereof.
particular,topolysulfurizedolefinsusedinlubricating10Preferably,theolefinsarebranched-chainolefins
oilcompositionsandtoamethodforpreparingsame.suchasisobutene,2-methyl小butene,2-methyl-2-
Sulfurizedolefinsareusedinlubricantssuchascrank-butene,2-methyl-2pentene,andthelike.Moreprefera-
caseoilandgearlubricantstoprovideextremepressurebly,theethylenicdoublebondadjoinsatertiarycarbon
properties.atomsuchasisobutylene,themostpreferredolefin
Papayetal,U.S.Pat.No.4,204,969describessucha15Thefirststagereactionispreferablyconductedby
productinwhichsulfurmonochlorideisreactedwithaddingtheolefintothesulfurmonochloride.Theolefin
analiphaticmonoolefintoobtainanintermediatewhichcanbeaddedasagasorliquid.Preferably,itisadded
isreactedwithsulfurandsodiumsulfide.beneaththesurfaceofthesulfurmonochlorideasa
Oneprobleminthefieldofsulfurizedolefinadditivesliquid.
usedforimprovingtheextremepressurepropertiesof20Inpractice,theolefinisaddeduntilthereactionwith
lubricantscontinuestobethedevelopmentofasulfu-thesulfurmonochloridestopsasindicatedbylossof
rizedpolyolefinadditivewhichissufficientlysolubleinexotherm.Anamountofabout0.45-1.5grammolesof
bothmineraloilsandsyntheticoils(particularlythoseolefinforeach0.3-0.75grammoleofsulfurmonochlo-
ofthepolyalphaolefintype)tobeusableasextremerideusuallysuffices.Apreferredamountisabout
pressureadditives.251.7-2.0grammolesofolefinpergrammoleofsulfur
ThisproblemisaddressedinBornetal,U.S.Pat.No.monochloride.
4,645,610whichteachesthatthesolubilityofsuchole-Asstatedhereinabove,thereactionoftheolefinand
finpolysulfideadditivesinbothmineralandsyntheticthesulfurmonochlorideiscarriedoutinthepresenceof
oilsisinverselyproportionaltothesulfurcontentoftheminoramountsofanactiveLewisacid.TheLewisacid
additive.Thatis,asthesulfurcontentoftheadditive30canbeaddedtothesulfurmonochlorideinitially,added
increasesthesolubilityoftheadditiveinbothmineraltothereactionmixturecontinuouslyorperiodically
andsyntheticoils(particularlythoseofthepolyal-duringthecourseoftheolefinaddition,oritcanbe
phaolefintype)decreases.Reportedly,olefinpolysul-mixedwiththeolefinandaddedtogetherwiththeole-
fideadditivesofhighsulfurcontenthavingenhancedfm.Thepreferredmodeofadditionistoaddtheentire
solubilityinbothmineralandsyntheticoilscanbeob-35amountinitiallytothesulfurmonochlorideandthen
tamedaccordingtoBornetalbycontactinganadditionaddtheolefin.
productproducedbythereactionofatleastoneali-ThetermactiveLewisacidreferstoanyLewisacid
phaticmonoolefincontaining2to5carbonatomsandorelectronacceptorwhichwhenutilizedinaccordance
sulfurmonochlorideordichloridewithahydrocarbylwiththeteachingssetforthhereinproducesanadduct
halideandatleastonesulfurcompoundselectedfrom40which,aftersulfurization,affordsalubricantadditive
sulfides,hydrosulfidesandpolysulfidesofalkalimetals,possessingsufficientsolubilityineithermineralorsyn-
ammoniumoralkaline-earthmetalsandusuallyelemen-theticoils(especiallythoseofthepolyalphaolefintype)
talsulfurinanaqueousoraqueousalcoholicmediumattofunctionasanextremepressureadditiveinsuchoils.
certainreactionconditions.ExamplesofLewisacidswhichcanbeusedintheprac-
Griffinetal,U.S.Pat.No.4,563,302alsoreportsthat45ticeoftheinventionincludealuminumbromide,alumi-
sulfurizedolefinshavingimprovedsolubilityinlubri-numfluoride,borontrifluoride,borontrichloride,stan-
Gatingoils(especiallyinalpha-olefinoligomersyntheticnicchloride,titaniumtetrachloride,ferricchloride,
oils)canbeobtainedbyreactinganalkylmercaptan,ferricbromide,aluminumchloride,andthelike.Ferric
sulfur,sodiumsulfideand,optionally,sodiumhydrosul-chlorideisthepreferredLewisacidforuseintheprac-
fideinanaqueousalcoholmediumwithanadductpre-50ticeofthepresentinventionandisreadilyavailable
paredbyreactingamonoolefinwithsulfurmonochlo-commercially.
rideorsulfurdichloride.TheamountofLewisacidusedinthepracticeofthe
___________________________inventionisanamountwhichwillproduceolefinpolv-
一一~一~-----一----一一一’--一’sutnaesofsutnctentsomouttymmmeratanasyntneuc
Unexpectedly,ithasnowbeendiscoveredthatsulfu-55oilsthattheycanbeusedinsuchoilsaseffectiveex-
rizedolefiniccompoundswhicharesolubleinbothtremepressureadditives.Theamountmayvarywith
mineralandsyntheticoilsoflubricatingviscosityatthespecificLewisacidused.Theamountrequiredis
concentrationssufficienttoimprovetheextremepres-readilydeterminedexperimentallybyaddingthepartic-
surepropertiesofsuchoils(includingthoseofthepp-ularLewisacidselectedforuseinthepreparationofthe
lyalphaolefintype)canbeobtainedbyreactingsulfur60adducttothereactionmixtureofsulfurmonochloride
monochloridewithaliphaticmonoolefininthepresenceandmonoolefinuntilanadductisproduced,which,as
ofminoramountsofanactiveLewisacidandthereafterindicatedpreviously,aftersulfurizationaffordsanaddi-
reactingtheadductsoproducedwithsulfurandsodiumtivepossessingthedesiredsolubilityandextremepres-
sulfideinaqueousalkanol.Theadduct,producedinthissurepropertiesbothinmineralandsyntheticoils.
fashion,aftersulfurizationaffordsalubricantadditive65Ingeneral,minoramountswhichcanvaryfrom
sufficientlysolubleinbothmineralandsyntheticoilstoabout0.025percenttoabout5.0percentbyweightof
beusableasanextremepressureadditiveineithertypeLewisacidbasedontheweightofsulfurmonochloride
oflubricant.areusedintheinvention.Apreferredamountisfrom
3
4
about0.05percenttoabout3.0percentbyweight.The
mostpreferredisabout0.1percentbyweight.
Thefirststagereactioncanbeconductedatanytem-
peraturehighenoughtocausethereactiontoproceed,
butnotsohighastocausedecompositionofthereac-
tamsorproducts.Ausefulrangeisabout300-1000C.A
morepreferredrangeisabout400-750C.andamost
preferredrangeisabout500-600C.
Thefirststagereactionshouldbeconductedfora
timesufficienttocompletethereactionbetweenthe
sulfurmonochlorideandolefin.Thisisusuallylimited
byheatremoval.Olefinfeedrateispreferablycon-
trolledtoholdthetemperaturewithinthedesired
range.Whenthesulfurmonochloridehasbeencon-
sumed,thetemperaturewilldrop.Externalheatmaybe
addedtocontinuethereactionforafurthertime,but
thisdoesnotappeartobenecessary.Theoverallti
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